伏安法教程題解

Publisher's Foreword
Glossary of Symbols and Abbreviations
1 Equilibrium Electrochenustry and the Nernst Equation
1.1 CeIIThermodynamics
1.2 TheNernstEquation
1.3 TheNernstEquation
1.4 TheNernstEquation
1.5 Theory ofthe Nernst Equation
1.6 The Debye-HuckeILimiting Law
1.7 CeIIReaction and Equilibrium Constant
1.8 CelIReaction and Equilibrium Constant
1.9 CelIReaction and Solubility Product
1.10 CeIIReaction andpKa
1.11 CeIIThermodynamics and Temperature
1.12 CellThermodynamics andTemperature
1.13 CeIIEnergetics
1.14 CeIIEMFandpH
1.15 CellReactionandEquilibria
1.16 CelIReaction and Kw
1.17 CeIIReaction and Disproportionation
1.18 FuelCelIEnergetics
1.19 FueICeUEnergetics
1.20 The Influence ofTemperature on the Self-Ionisation ofWater
1.21 CellReaction and Complexation
1.22 Reference Electrodes
1.23 FormalPotentials
1.24 FormaIPotentials
1.25 StandardPotentialsandpH
1.26 StandardPotentials andpH
1.27 Standard Potentials andpH

2 ElectrodeKinetics
2.1 Faraday's Laws ofElectrolysis
2.2 Electrodeposition
2.3 TafeIAnalysis: One-Electron Processes
2.4 TafelAnalysis:ElectrochemicallyReversibleProcesses
2.5 TafeIAnalysis:Mass Transport Correction
2.6 TafeIAnalysis:Two-Electron Processes
2.7 The Butler-Volmer Equation and the Nernst Equation
2.8 The Hydrogen Evolution Reaction
2.9 Requirement for Supporting Electrolyte
2.10 Frumkin Corrections
2.11 Marcus Theory and Standard Electrochemical Rate Constants
2.12 Marcus Theoryand Butler-Volmer Kinetics
2.13 Marcus Theory and the Role ofSolvent
2.14 Marcus Theory and thelnverted Region

3 Diffusion
3.1 Fick's LawsofDiffusion
3.2 Fick's Laws ofDiffusion
3.3 DiffusionDistances
3.4 TheCottrelIEquation
3.5 Derivation ofthe CottreIIEquation
3.6 Diffusion and Root-Mean-Square Displacement

4 CyclicVoltammetry at Macroelectrodes
4.1 CyclicVoltammetry: Electrochemically Reversible Voltammetry
4.2 CyclicVoltammetry:Electrochemicallylrreversible Voltammetry
4.3 ReversiblevsIrreversibleVoltammetry
4.4 VoltammetricDiagnostics
4.5 VoltammetryandScan RateEffects
……